Polypyrrole self-assembled monolayers and electrostatically assembled multilayers on gold and platinum electrodes for molecular junctions (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Polypyrrole self-assembled monolayers and electrostatically assembled multilayers on gold and platinum electrodes for molecular junctions (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Alternative label

• Vercelli B., Zotti G., Berlin A., Grimoldi S. (2006)
  Polypyrrole self-assembled monolayers and electrostatically assembled multilayers on gold and platinum electrodes for molecular junctions
  in Chemistry of materials
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Vercelli B., Zotti G., Berlin A., Grimoldi S. (literal)

Pagina inizio

• 3754 (literal)

Pagina fine

• 3763 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 18 (literal)

Rivista

• Chemistry of materials (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto per l'Energetica e le Interfasi Istituto di Scienze e Tecnologie Molecolari (literal)

Titolo

• Polypyrrole self-assembled monolayers and electrostatically assembled multilayers on gold and platinum electrodes for molecular junctions (literal)

Abstract

• Self-assembled monolayers (SAMs) and electrostatically assembled multilayers of some soluble polypyrroles (including a thiol-functionalized polypyrrole) were produced on gold and platinum electrodes. Gold and platinum surfaces were used either bare or primed with an anionic monolayer of 3-mercaptopropylsulfonate or Nafion. Poly(sodium-p-styrenesulfonate) and Nafion were used as polyanions for electrostatic self-assembly (ESA). The layers were investigated by cyclic voltammetry, infrared reflection absorption spectroscopy, quartz crystal microbalance, and atomic force microscopy (AFM). ESA proceeds with a growth rate that is linear with the number of bilayers and particularly high (stored charge 30-60 íC cm-2 bilayer-1) with Nafion, which appears to be the primer for all the investigated polypyrroles. Gold-polymer-gold junctions, formed by contact between a polypyrrole SAM on gold and a goldcoated AFM tip, rectify current in polypyrrole sulfosuccinate, whereas they are ohmic with Simmons characteristics in poly(N-hexylcyclopenta[c]pyrrole). In the former case alternation of rectifying and ohmic characteristics is observed with progressive ESA. (literal)

Prodotto di

• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)
• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Materiali per elettronica molecolare e optoelettronica (PM.P04.001.003) (Modulo)

Autore CNR

• GIANNI ZOTTI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)
• BARBARA VERCELLI (Unità di personale interno)
• ANNA BERLIN (Unità di personale interno)

Incoming links:

Prodotto

• Istituto di scienze e tecnologie molecolari (ISTM) (Istituto)
• Institute of Condensed Matter Chemistry and Energy Technologies (ICMATE) (Istituto)
• Nanostrutture funzionali su superfici elettrodiche (ET.P06.011.002) (Modulo)
• Materiali per elettronica molecolare e optoelettronica (PM.P04.001.003) (Modulo)

Autore CNR di

• ANNA BERLIN (Unità di personale interno)
• BARBARA VERCELLI (Unità di personale interno)
• SANDRO ZECCHIN (Persona)
• GIANNI ZOTTI (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chemistry of materials (Rivista)