Lyman and Balmer emission following core excitations in methane and ammonia molecules (Articolo in rivista)

Type
Label
  • Lyman and Balmer emission following core excitations in methane and ammonia molecules (Articolo in rivista) (literal)
Anno
  • 2007-01-01T00:00:00+01:00 (literal)
Alternative label
  • K. Jakubowska, G. Vall-llosera, A. Kivimaki, M. Coreno, E. Melero Garcia, M. Stankiewicz, E. Rachlew (2007)
    Lyman and Balmer emission following core excitations in methane and ammonia molecules
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • K. Jakubowska, G. Vall-llosera, A. Kivimaki, M. Coreno, E. Melero Garcia, M. Stankiewicz, E. Rachlew (literal)
Pagina inizio
  • 1489 (literal)
Pagina fine
  • 1500 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 40 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • AlbaNova Univ Ctr, Royal Inst Technol, Dept Phys, S-10691 Stockholm, Sweden; CNR, INFM, Lab Nazl TASC, I-34012 Trieste, Italy; CNR, IMIP, I-00016 Monterotondo, Italy; Jagiellonian Univ, Inst Fizyki Mariana Smoluchowskiego, PL-30059 Krakow, Poland (literal)
Titolo
  • Lyman and Balmer emission following core excitations in methane and ammonia molecules (literal)
Abstract
  • The intensities of hydrogen Lyman-alpha and Balmer series emission lines as a result of photoexcitation of free CH4 and NH3 molecules at the C 1s and N 1s edges have been measured. For methane, the total fluorescence yield in the visible region ( 300 - 650 nm) was also recorded. Excitation functions of the Balmer lines show relative intensity enhancement of Balmer-beta emission in comparison with Balmer-alpha at higher core- to- Rydberg excitations. The Lyman-alpha emission intensity, in general, follows the relations observed in the corresponding total ion yield measurements. Additionally, the Balmer-gamma and -delta yields were measured for ammonia molecules and they show intensity maxima at photon energies shifted closer to the N 1s threshold than Balmer-alpha and -beta. A quantum defect analysis is performed to find out which core excitations are responsible for this enhanced intensity. Dissociation pathways leading to the emission in H atoms are discussed. (literal)
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