Pd nanoparticle catalyzed heck arylation of 1,1-disubstituted alkenes in ionic liquid. Study on factors affecting the regioselectivity of the coupling process (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Pd nanoparticle catalyzed heck arylation of 1,1-disubstituted alkenes in ionic liquid. Study on factors affecting the regioselectivity of the coupling process (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Alternative label

• Calo´ V., Nacci A., Monopoli A., Detomaso A., Iliade P. (2003)
  Pd nanoparticle catalyzed heck arylation of 1,1-disubstituted alkenes in ionic liquid. Study on factors affecting the regioselectivity of the coupling process
  in Organometallics
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Calo´ V., Nacci A., Monopoli A., Detomaso A., Iliade P. (literal)

Pagina inizio

• 4193 (literal)

Pagina fine

• 4197 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 22 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note

• fascicolo (21) (literal)

Note

• ISI Web of Science (WOS) (literal)

Titolo

• Pd nanoparticle catalyzed heck arylation of 1,1-disubstituted alkenes in ionic liquid. Study on factors affecting the regioselectivity of the coupling process (literal)

Abstract

• The Heck reaction of neutral or electron-rich aryl bromides with the 1,1-disubstituted olefins butyl methacrylate and á-methylstyrene catalyzed by Pd nanoparticles in tetrabutylammonium bromide as solvent and tetrabutylammonium acetate as base leads to a prevalent formation of the terminal olefin. In contrast, reaction of p-bromoacetophenone leads to the internal olefin. Whereas the solvent stabilizes the metal nanoclusters, the base is responsible for a fast neutralization of the PdH impeding the hybride readdition to reaction products and avoiding the olefin interconversion. The terminal olefins are efficiently converted into more stable internal E isomers by using tetrabutylammonium pivalate as catalyst. (literal)

Prodotto di

• Water research institute (IRSA) (Istituto)
• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• ANTONIA DETOMASO (Persona)

Incoming links:

Prodotto

• Water research institute (IRSA) (Istituto)
• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR di

• ANTONIA DETOMASO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)