Main Group Element Net to a T (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Main Group Element Net to a T (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/ic0353211 (literal)

Alternative label

• Ienco, Andrea; Proserpio, Davide M.; Hoffmann, Roald (2004)
  Main Group Element Net to a T
  in Inorganic chemistry
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Ienco, Andrea; Proserpio, Davide M.; Hoffmann, Roald (literal)

Pagina inizio

• 2526 (literal)

Pagina fine

• 2540 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 43 (literal)

Rivista

• Inorganic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Cornell Univ, Baker Lab, Dept Chem & Chem Biol, Ithaca, NY 14853 USA Univ Milan, Dipartimento Chim Strutt & Stereochim Inorgan, I-20133 Milan, Italy (literal)

Titolo

• Main Group Element Net to a T (literal)

Abstract

• T-shaped nets (three-coordinated nets with an angular metric, bond angles near 90degrees, 90degrees, 180degrees) are found in a number of extended structures. We explore in this paper the geometrical and electronic consequences of a stricter T-shape metric, where the distances between the vertices of the net are approximately equal and in the range of a chemical bond. Every atom in such a net has a T-shaped environment. One can think of these nets as extensions of BrF3 or of substructures of various extended tellurium compounds. Several construction principles are found which allow an enumeration of a variety of one-, two-, and three-dimensional T-shape nets; not every three-coordinated net lends itself to the stricter geometrical and distance metric. Not everything is possible; there are no zero-dimensional T-nets, and none made entirely of three atom segments. Previous ideas on electron-rich multicenter bonding lead to a simple way of calculating the magic electron counts for each net; these lie in the range of 6 to 6.67. (literal)

Prodotto di

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)
• Processi catalitici sostenibili ed innovativi in ambito macromolecolare (PM.P02.005.001) (Modulo)

Autore CNR

• ANDREA IENCO (Unità di personale interno)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)
• Processi catalitici sostenibili ed innovativi in ambito macromolecolare (PM.P02.005.001) (Modulo)

Autore CNR di

• ANDREA IENCO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry (Rivista)