Selective oxidation of acetylenic 1,4-diols with Dioxiranes in comparison with the Methyltrioxorhenium-Hydrogen Peroxide oxidant (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Selective oxidation of acetylenic 1,4-diols with Dioxiranes in comparison with the Methyltrioxorhenium-Hydrogen Peroxide oxidant (Articolo in rivista) (literal)

Anno

• 2004-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.tetlet.2004.09.110 (literal)

Alternative label

• D'Accolti L.; Fiorentino M.; Fusco C.; Crupi P.; Curci R (2004)
  Selective oxidation of acetylenic 1,4-diols with Dioxiranes in comparison with the Methyltrioxorhenium-Hydrogen Peroxide oxidant
  in Tetrahedron letters
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• D'Accolti L.; Fiorentino M.; Fusco C.; Crupi P.; Curci R (literal)

Pagina inizio

• 8575 (literal)

Pagina fine

• 8578 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 45 (literal)

Rivista

• Tetrahedron letters (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 4 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Dipartimento Chimica, Università di Bari, C.N.R.--Istituto di Chimica dei Composti Organometallici (ICCOM) (literal)

Titolo

• Selective oxidation of acetylenic 1,4-diols with Dioxiranes in comparison with the Methyltrioxorhenium-Hydrogen Peroxide oxidant (literal)

Abstract

• Dimethyldioxirane and its trifluoro analog were employed to achieve selectively the direct transformation of hex-3-yne-2,5-diol and 1,4-diphenyl-2-butyne-1,4-diol into carbonyls, e.g., I (R = Me, Ph), leaving the carbon-carbon triple bond moiety untouched. The results were compared with those recorded in the analogous oxidn. using the methyltrioxorhenium/H2O2 homogeneous system. The powerful methyl(trifluoromethyl)dioxirane was the reagent of choice to achieve optimum yields of the target alkyne-1,4-diones, which were extremely versatile synthons. (literal)

Prodotto di

• processi e metodologie sostenibili in chimica organica per la sintesi di nuove piattaforme molecolari (PM.P03.011.001) (Modulo)
• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• CATERINA FUSCO (Persona)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)
• processi e metodologie sostenibili in chimica organica per la sintesi di nuove piattaforme molecolari (PM.P03.011.001) (Modulo)

Autore CNR di

• CATERINA FUSCO (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Tetrahedron letters (Rivista)