http://www.cnr.it/ontology/cnr/individuo/prodotto/ID16713
Enantioselective Routes to Sulfoxides Based Upon the Use of Carbanionic Leaving Groups (Articolo in rivista)
- Type
- Label
- Enantioselective Routes to Sulfoxides Based Upon the Use of Carbanionic Leaving Groups (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1002/ejoc.2003.00497 (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Capozzi M.A.M., Cardellicchio C., Naso F. (literal)
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- Rivista
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Titolo
- Enantioselective Routes to Sulfoxides Based Upon the Use of Carbanionic Leaving Groups (literal)
- Abstract
- Several carbanionic leaving groups can be easily displaced from the sulfinyl group by organometallic reagents. The reaction follows a highly stereoselective course of inversion of configuration. Provided that a ready route to the precursor sulfinyl compound is available (e.g. an enantioselective ox-idation of the corresponding sulfide), the process can be transformed into an easy and versatile procedure for the ster-eoselective synthesis of sulfoxides. (literal)
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