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Dissociative double photoionization of N-2 using synchrotron radiation: Appearance energy of the N2+ dication (Articolo in rivista)
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- Label
- Dissociative double photoionization of N-2 using synchrotron radiation: Appearance energy of the N2+ dication (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1063/1.2714521 (literal)
- Alternative label
Franceschi, P; Ascenzi, D; Tosi, P; Thissen, R; Zabka, J; Roithova, J; Ricketts, CL; De Simone, M; Coreno, M (2007)
Dissociative double photoionization of N-2 using synchrotron radiation: Appearance energy of the N2+ dication
in The Journal of chemical physics
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Franceschi, P; Ascenzi, D; Tosi, P; Thissen, R; Zabka, J; Roithova, J; Ricketts, CL; De Simone, M; Coreno, M (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
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- ISI Web of Science (WOS) (literal)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Univ Trent, Dipartimento Fis, I-38050 Trento, Italy; Univ Paris 11, CNRS UMR 8000, Chim Phys Lab, F-91405 Orsay, France; Acad Sci Czech Republ, J Heyrovsky Inst Phys Chem, CR-18223 Prague, Czech Republic; Acad Sci Czech Republ, Inst Organ Chem & Biochem, CR-16610 Prague, Czech Republic; Univ London Univ Coll, Dept Chem, London WC1H 0AJ, England; CNR, INFM, Lab Nazl TASC, I-34012 Trieste, Italy; CNR, IMIP, Rome Branch, I-34012 Trieste, Italy (literal)
- Titolo
- Dissociative double photoionization of N-2 using synchrotron radiation: Appearance energy of the N2+ dication (literal)
- Abstract
- Photoionization cross sections for the production of the doubly charged ion N2+ from N-2 have been measured by means of synchrotron radiation in the photon energy range from 50 to 110 eV. The appearance energy for N2+ has been determined as 55.2 +/- 0.2 eV, i.e., about 1.3 eV higher than the spectroscopic dissociation limit leading to the charge asymmetric dissociation channel N2+(P-2)+N(S-4) at 53.9 eV. The onset of a second threshold at 59.9 +/- 0.2 eV is detected and the energy dependence of photoion intensities near the threshold regions is interpreted in terms of the Wannier theory. The production of the N2+ dication is discussed in terms of direct and indirect mechanisms for dissociative charge asymmetric photoionization and by comparison with the potential energy curves of the intermediate N-2(2+) dication. Experimental evidences for the opening of the Coulomb explosion channel N2++N+ at high photon energies are provided by measuring the kinetic energy release spectra of N2+ fragments at selected photon energies. (c) 2007 American Institute of Physics. (literal)
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