Novel results on thiodiacetate zinc(II) complexes: Synthesis and structure of [Zn(tda)(phen)]2 H2O (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Novel results on thiodiacetate zinc(II) complexes: Synthesis and structure of [Zn(tda)(phen)]2 H2O (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.inoche.2005.10.021 (literal)

Alternative label

• Grirrane, Abdessamad; Pastor, Antonio; Alvarez, Eleuterio; Mealli, Carlo; Ienco, Andrea; Galindo, Agustin (2006)
  Novel results on thiodiacetate zinc(II) complexes: Synthesis and structure of [Zn(tda)(phen)]2 H2O
  in Inorganic chemistry communications
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Grirrane, Abdessamad; Pastor, Antonio; Alvarez, Eleuterio; Mealli, Carlo; Ienco, Andrea; Galindo, Agustin (literal)

Pagina inizio

• 160 (literal)

Pagina fine

• 163 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 9 (literal)

Rivista

• Inorganic chemistry communications (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Univ Sevilla, Dept Quim Inorgan, E-41071 Seville, Spain Univ Sevilla, CSIC, Inst Invest Quim, E-41092 Seville, Spain CNR, ICCOM, I-50019 Florence, Italy (literal)

Titolo

• Novel results on thiodiacetate zinc(II) complexes: Synthesis and structure of [Zn(tda)(phen)]2 H2O (literal)

Abstract

• Novel zinc thiodiacetate complex [Zn(tda)(H2O)](n) (1) (tda = S(CH2COO)(2)(2-)) was obtained from the reaction of aqueous solutions of 2 zinc dichloride with a 1: 1 mixture of Na2CO3 and thiodiacetic acid. Complex 1 is a different hydrate compound with respect to the known species [Zn(tda)(H2O)(3)] center dot H2O. The selective formation of 1 or [Zn(tda)(H2O)(3)] center dot H2O can be achieved by controlling the crystallization conditions and it is even possible to interconvert the two hydrate compounds by fast or slow crystallization processes. The reaction of 1 with o-phenanthroline (phen) gave the dinuclear compound [Zn(tda)(phen)](2) center dot 5H(2)O (2), which was identified by X-ray analysis. The water crystallization molecules are interconnected by hydrogen bonds and they are aligned inside channels, which are parallel to the c-axis. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• CARLO MEALLI (Persona)
• ANDREA IENCO (Persona)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• http://www.cnr.it/ontology/cnr/individuo/modulo/ID2414

Autore CNR di

• ANDREA IENCO (Persona)
• CARLO MEALLI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Inorganic chemistry communications (Rivista)