Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) (Articolo in rivista)

Type
Label
  • Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1016/j.inoche.2006.01.003 (literal)
Alternative label
  • Bolaño, Sandra; Albinati, Alberto; Bravo, Jorge; Gonsalvi, Luca; Peruzzini, Maurizio (2006)
    Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)
    in Inorganic chemistry communications; Elsevier BV, Amsterdam (Paesi Bassi)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bolaño, Sandra; Albinati, Alberto; Bravo, Jorge; Gonsalvi, Luca; Peruzzini, Maurizio (literal)
Pagina inizio
  • 360 (literal)
Pagina fine
  • 363 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 9 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR, Universita' di Milano (literal)
Titolo
  • Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane) (literal)
Abstract
  • Boronation of the water soluble phosphine PTA (PTA = l,3,5-triaza-7-phosphaadamantane) in dry THF easily affords the N-boronated adduct N-B-PTABH3 which represents the first N-coordinated adduct of this popular water soluble phosphine (N-B-PTABH3 = 1-boranyl-1,3,5-triaza-7-phosphaadamantane). In situ 31P NMR spectroscopy suggests the occurrence of a stepwise boronation resulting in the addition of as many as four equivalents of BH3 to PTA to give the polyboranyl species Nx, Py-B-PTA(BH3)(x+y) (x = 1-3, y = 0, 1). Hydrolysis of the monoboranyl adduct occurs slowly in the presence of water yielding back PTA and boric acid, H3BO3. (literal)
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