Photoelectron spectroscopy of sulfur L levels in the SF5CF3 molecule (Articolo in rivista)

Type
Label
  • Photoelectron spectroscopy of sulfur L levels in the SF5CF3 molecule (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Alternative label
  • Kivimaki, A; Ruiz, JA; Coreno, M; Stankiewicz, M; Fronzoni, G; Decleva, P (2008)
    Photoelectron spectroscopy of sulfur L levels in the SF5CF3 molecule
    in Chemical physics (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Kivimaki, A; Ruiz, JA; Coreno, M; Stankiewicz, M; Fronzoni, G; Decleva, P (literal)
Pagina inizio
  • 202 (literal)
Pagina fine
  • 208 (literal)
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  • 353 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • \"[Kivimaki, A.; Coreno, M.] CNR, INFM, Lab Nazl TASC, I-34012 Trieste, Italy; [Alvarez Ruiz, J.] CSIC, Inst Quim Fis Rocasolano, Dept Quim Laser, E-28006 Madrid, Spain; [Coreno, M.] CNR, IMIP, I-00161 Rome, Italy; [Stankiewicz, M.] Uniwersytet Jagiellonski, Inst Fizyki Mariana Smoluchowskiego, PL-30059 Krakow, Poland; [Fronzoni, G.; Decleva, P.] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy; [Fronzoni, G.; Decleva, P.] INFM DEMOCRITOS, Trieste, Italy; [Fronzoni, G.; Decleva, P.] INSTM CRIMSON, Trieste, Italy (literal)
Titolo
  • Photoelectron spectroscopy of sulfur L levels in the SF5CF3 molecule (literal)
Abstract
  • The photoelectron spectra of the S 2s and S 2p main lines as well as of the S 2p shake-up satellites of the SF5CF3 molecule have been measured using synchrotron radiation excitation. The main spectral lines have been compared to those of the closely-related SF6 molecule. The S 2p binding energies in SF5CF3 were obtained in reference to those in SF6, while the S 2s binding energies of both SF5CF3 and SF6 were determined with respect to the Ar 2p-(1) states. The intensity behavior of the spin-orbit-split S 2p photoelectron lines of SF5CF3 was studied in the region of the shape resonance whose maximum is located some 15 eV above the S 2p threshold. The S 2p shake-up satellite spectrum of SF5CF3 has been interpreted with the aid of ab initio configuration interaction calculations within the sudden-limit approximation. (C) 2008 Elsevier B.V. All rights reserved. (literal)
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