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Electrochemical Synthesis of the sigma-Aryl Complex [NiBr(Mes)(bpy)] and Its Use as Catalyst Precursor for the Oligomerization of Ethylene (Mes = 2,4,6-Trimethylphenyl, bpy = 2,2-Bipyridine) (Articolo in rivista)
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- Electrochemical Synthesis of the sigma-Aryl Complex [NiBr(Mes)(bpy)] and Its Use as Catalyst Precursor for the Oligomerization of Ethylene (Mes = 2,4,6-Trimethylphenyl, bpy = 2,2-Bipyridine) (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1016/j.poly.2005.10.032 (literal)
- Alternative label
Dmitry G. Yakhvarov,
Damir I. Tazeev,
Oleg G. Sinyashin,
Giuliano Giambastiani,
Claudio Bianchini,
Anna M. Segarra,
Peter Lonnecke,
Evamarie Hey-Hawkins (2006)
Electrochemical Synthesis of the sigma-Aryl Complex [NiBr(Mes)(bpy)] and Its Use as Catalyst Precursor for the Oligomerization of Ethylene (Mes = 2,4,6-Trimethylphenyl, bpy = 2,2-Bipyridine)
in Polyhedron; pergamon press, new york (Stati Uniti d'America)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Dmitry G. Yakhvarov,
Damir I. Tazeev,
Oleg G. Sinyashin,
Giuliano Giambastiani,
Claudio Bianchini,
Anna M. Segarra,
Peter Lonnecke,
Evamarie Hey-Hawkins (literal)
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- A.E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, 420088 Kazan, Russian Federation
Istituto di Chimica dei Composti Organo Metallici, Area di Ricerca del CNR, 50019 Sesto Fiorentino (FI), Italy
Institut fur Anorganische Chemie, Universitat Leipzig, Johannisallee 29, D-04103 Leipzig, Germany (literal)
- Titolo
- Electrochemical Synthesis of the sigma-Aryl Complex [NiBr(Mes)(bpy)] and Its Use as Catalyst Precursor for the Oligomerization of Ethylene (Mes = 2,4,6-Trimethylphenyl, bpy = 2,2-Bipyridine) (literal)
- Abstract
- The oxidative addition of mesityl bromide either to electrochemically generated [Ni(bpy)] or to [Ni(COD)2] (COD = 1,5-cyclooctadiene) in the presence of 2,20-bipyridine allows the selective, high-yield synthesis of the r-aryl complex [NiBr(Mes)(bpy)] (Mes = 2,4,6-trimethylphenyl, bpy = 2,20-bipyridine), which is an efficient catalyst precursor for the oligomerization of ethylene to even-numbered olefins in the C4-C26 range with a Schulz-Flory distribution. (literal)
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