Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation (Articolo in rivista)

Type

• Articolo in rivista (Classe)
• Prodotto della ricerca (Classe)

Label

• Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1016/j.polymer.2006.05.049 (literal)

Alternative label

• Augier S., Coiai S., Gragnoli T., Passaglia E., Pradel J.-L., Flat J.-J. (2006)
  Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation
  in Polymer (Guildford)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Augier S., Coiai S., Gragnoli T., Passaglia E., Pradel J.-L., Flat J.-J. (literal)

Pagina inizio

• 5243 (literal)

Pagina fine

• 5252 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 47 (literal)

Rivista

• Polymer (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• a Department of Chemistry and Industrial Chemistry, University of Pisa, Via Risorgimento 35, 56126 Pisa, Italy b CNR-ICCOM Pisa Section, Department of Chemistry and Industrial Chemistry, University of Pisa, Via Risorgimento 35, 56126 Pisa, Italy c ARKEMA CERDATO 27470 Serquigny, France. (literal)

Titolo

• Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation (literal)

Abstract

• The occurrence of significant degradation by b-scission reaction is a severe drawback affecting the classical procedure of polypropylene (PP) functionalization in the melt with maleic anhydride (MAH) or derivatives and free radical initiators. The present work deals with the control of the PP blocks degradation by using a specially designed furan derivative, butyl 3-(2-furyl) propenoate (BFA), as coagent able to control the PP blocks scission during PP functionalization process. More specifically MAH or BFA were used as functionalizing reagents for a propylene/ethylene 77/23 mol% semi-block copolymer (PPC) either separately or as mixture (MAH/BFA) with different molar ratios. The PPC functionalized samples were then characterized by determining the number of grafted groups (functionalization degree FD) and the molecular weight (MW). Finally, the effect of the feed conditions on the process and on functionalized PPC properties are discussed by hypothesizing a reaction mechanism, which takes into account all the occurring parallel reactions. (literal)

Prodotto di

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Sviluppo e applicazioni di metodologie preparative di materiali polimerici funzionali nanostrutturati in processi di reactive blending (PM.P03.015.005) (Modulo)
• Processi di post-modifica e miscelazione reattiva per la preparazione di sistemi macromolecolari multifasici, nanostrutturati e funzionali (PM.P02.005.006) (Modulo)

Autore CNR

• ELISA PASSAGLIA (Persona)
• SERENA COIAI (Persona)

Insieme di parole chiave

• Keywords of "Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Processi di post-modifica e miscelazione reattiva per la preparazione di sistemi macromolecolari multifasici, nanostrutturati e funzionali (PM.P02.005.006) (Modulo)
• Sviluppo e applicazioni di metodologie preparative di materiali polimerici funzionali nanostrutturati in processi di reactive blending (PM.P03.015.005) (Modulo)

Autore CNR di

• ELISA PASSAGLIA (Persona)
• SERENA COIAI (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Polymer (Rivista)

Insieme di parole chiave di

• Keywords of "Coagent assisted polypropylene radical functionalization: monomer grafting modulation and molecular weight conservation" (Insieme di parole chiave)