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Self-assemblies of chiral p-haloaryl sulfoxides through C-H
O short contacts and halogen involving interactions (Articolo in rivista)
- Type
- Label
- Self-assemblies of chiral p-haloaryl sulfoxides through C-H
O short contacts and halogen involving interactions (Articolo in rivista) (literal)
- Anno
- 2006-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/b607545b (literal)
- Alternative label
Naso F., Cardellicchio C., Capozzi M.A.M., Capitelli F., Bertolasi V. (2006)
Self-assemblies of chiral p-haloaryl sulfoxides through C-H
O short contacts and halogen involving interactions
in New journal of chemistry (1987)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Naso F., Cardellicchio C., Capozzi M.A.M., Capitelli F., Bertolasi V. (literal)
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- ISI Web of Science (WOS) (literal)
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- 1. Univ Bari, Dipartimento Chim, Ist Chim & Composti Organomet, Consiglio Nazl Ric, I-70126 Bari, Italy
2. Univ Studi Foggia, Dipartimento Sci Agroambientali Chim & Difesa Veg, I-71100 Foggia, Italy
3. CNR, Ist Cristallog, I-70126 Bari, Italy
4. Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy
5. Univ Ferrara, Ctr Strutturist Diffrattometr, I-44100 Ferrara, Italy (literal)
- Titolo
- Self-assemblies of chiral p-haloaryl sulfoxides through C-H
O short contacts and halogen involving interactions (literal)
- Abstract
- Single crystal X-ray structure determination of four crystals of alkyl or aryl p-haloaryl sulfoxides is reported. Intramolecular short contacts between the ortho-hydrogen of the aryl ring and the oxygen of the sulfinyl group were found to determine the conformations of the sulfoxides. On the other hand, in the absence of classical hydrogen bond donors, crystal packing arrangements are the results of intermolecular aryl hydrogen-oxygen short contacts and of interactions involving halogen atoms. From a comparison of the structures of the investigated sulfoxides with other literature data, the crystal packings of these types of compound appear to derive from a complex balance among different interactions. (literal)
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