A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane) (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane) (Articolo in rivista) (literal)

Anno

• 2006-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1021/om051099r (literal)

Alternative label

• Phillips, Andrew D.; Bolaño, Sandra; Bosquain, Sylvain S.; Daran, Jean-Claude; Malacea, Raluca; Peruzzini, Maurizio; Poli, Rinaldo; Gonsalvi, Luca (2006)
  A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane)
  in Organometallics (Online); ACS, American chemical society, Washington, DC (Stati Uniti d'America)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Phillips, Andrew D.; Bolaño, Sandra; Bosquain, Sylvain S.; Daran, Jean-Claude; Malacea, Raluca; Peruzzini, Maurizio; Poli, Rinaldo; Gonsalvi, Luca (literal)

Pagina inizio

• 2189 (literal)

Pagina fine

• 2200 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://pubs.acs.org/doi/abs/10.1021/om051099r (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 25 (literal)

Rivista

• Organometallics (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 12 (literal)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• ICCOM-CNR; Laboratoire de Chimie de Coordination (UPR CNRS 8241), 205 Route de Narbonne, 31077 Toulouse Cedex 4, France (literal)

Titolo

• A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane) (literal)

Abstract

• The open cage ligands PTN(R) (PTN = 7-R-phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane; R = Me, Ph), derived from cage cleavage of the water-soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane), were used to synthesize neutral [RhCl(cod)(PTN(R)] (10) and [RhI(CO){PTN-(Me)}] (12) and cationic [Rh(cod){PTN(R)}][BArF4] (11) rhodium(I) complexes, which were comprehensively characterized both in solution and in the solid state (cod = 1,5-cyclooctadiene; BArF4 = B[3,5-(CF3)2C6H3]4). Two modes of coordination to the metal were identified, k1-P (for 10) and k2-P,N (11,12). For k1-P coordination, the free N donor site rests in close proximity to the Rh center imparted by the rigid PTN framework. The complexes were tested as catalysts for (biphasic) olefin hydroformylation and regioselective C=C bond reduction under transfer hydrogenation conditions, together with acetophenone hydrogenation. DFT calculations on simplified models helped to assess the bonding properties within the complexes and to determine the amount of cage strain that accompanies the structural modifications of the ligand when transformed from a k1-P to k2-P,N coordination mode. (literal)

Editore

• ACS, American chemical society (Editore)

Prodotto di

• Nuovi materiali per 'storage' e produzione di idrogeno (PM.P03.005.001) (Modulo)
• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)

Autore CNR

• LUCA GONSALVI (Unità di personale interno)
• ANDREW DOUGLAS PHILLIPS (Persona)
• SYLVAIN SERGE JEAN CLAUDE BOSQUAIN (Persona)
• MAURIZIO PERUZZINI (Unità di personale interno)

Insieme di parole chiave

• Parole chiave di "A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane)" (Insieme di parole chiave)

Incoming links:

Prodotto

• Istituto di chimica dei composti organo metallici (ICCOM) (Istituto)
• Nuovi materiali per 'storage' e produzione di idrogeno (PM.P03.005.001) (Modulo)

Autore CNR di

• LUCA GONSALVI (Unità di personale interno)
• MAURIZIO PERUZZINI (Unità di personale interno)
• SYLVAIN SERGE JEAN CLAUDE BOSQUAIN (Persona)
• ANDREW DOUGLAS PHILLIPS (Persona)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Organometallics (Rivista)

Editore di

• ACS, American chemical society (Editore)

Insieme di parole chiave di

• Parole chiave di "A New Class of Rhodium(I) k1-P and k2-P,N Complexes with Rigid PTN(R) Ligands (PTN = 7-Phospha-3-methyl-1,3,5-triazabicyclo[3.3.1]nonane)" (Insieme di parole chiave)