http://www.cnr.it/ontology/cnr/individuo/prodotto/ID16577
Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane] (Articolo in rivista)
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- Label
- Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane] (Articolo in rivista) (literal)
- Anno
- 2003-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1039/ b308388h (literal)
- Alternative label
Bianchini, Claudio; Gonsalvi, Luca; Oberhauser, Werner; Sémeril, David; Brüggeller, Peter; Gutman, Rene (2003)
Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane]
in Dalton transactions (2003. Print); Royal Society of Chemistry, Cambridge (Regno Unito)
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- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Bianchini, Claudio; Gonsalvi, Luca; Oberhauser, Werner; Sémeril, David; Brüggeller, Peter; Gutman, Rene (literal)
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- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- ICCOM-CNR; University of Innsbruck, Austria (literal)
- Titolo
- Schulz-Flory Oligomerisation of Ethylene by the Dinuclear Nickel(II) Complex Ni2Cl4[cis, trans, cis-tetrakis-(diphenylphosphino)cyclobutane] (literal)
- Abstract
- The binuclear nickel(II) complex Ni2Cl4(cyclo-tetraphos) (cyclo-tetraphos = cis, trans, cis-1,2,3,4-tetrakis-(diphenylphosphino)cyclobutane) forms, upon activation with MAO, an effective and robust catalyst for the oligomerisation of ethylene to Schulz-Flory distributions of C4-C14 olefins with a mechanism where both chain transfer and chain propagation are first order in ethylene. (literal)
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