Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis (Articolo in rivista)

Type
Label
  • Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner (2003)
    Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis
    in Dalton transactions (2003. Online)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Bianchini, Claudio; Meli, Andrea; Oberhauser, Werner (literal)
Pagina inizio
  • 2627 (literal)
Pagina fine
  • 2635 (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#descrizioneSinteticaDelProdotto
  • L' articolo è una review sui meccanismi di iniziazione, propagazione e terminazione nel processo di copolimerizzazione CO/etilene (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • ICCOM-CNR (literal)
Titolo
  • Catalyst design and mechanistic aspects of the alternating copolymerisation of ethene and carbon monoxide by diphosphine-modified palladium catalysis (literal)
Abstract
  • The article addresses fundamental mechanistic aspects related to the perfectly alternating copolymerisation of CO and ethene in MeOH through the analysis of both actual reactions catalysed by palladium(II)-diphosphine precursors and stoichiometric reactions with model compounds. Most recent in situ studies of CO/ethene copolymerisationb, applying high-pressure IR and NMR techniques, have been reviewed and commented. (literal)
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