Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies (Articolo in rivista) (literal)

Anno

• 2003-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/ejic.200390082 (literal)

Alternative label

• Hintermann, Lukas; Perseghini, Mauro, Barbaro, Pierluigi; Togni, Antonio (2003)
  Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies
  in European journal of inorganic chemistry (Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Hintermann, Lukas; Perseghini, Mauro, Barbaro, Pierluigi; Togni, Antonio (literal)

Pagina inizio

• 601 (literal)

Pagina fine

• 609 (literal)

Rivista

• European journal of inorganic chemistry (Rivista)

Note

• ISI Web of Science (WOS) (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Department of Chemistry, Swiss Federal Institute of Technology, ETH Hönggerberg, 8093 Zürich, Switzerland. ISSECC ? CNR, Via Jacopo Nardi 39, 50132 Firenze, Italy. (literal)

Titolo

• Complexes of Rhodium(I) and Iridium(I) with the Chiral Tridentate Phosphane Pigiphos: Structure and Reactivity Studies (literal)

Abstract

• The chiral ferrocenyltriphosphane Pigiphos [bis{(S)-1-[(R)-2-(diphenylphosphanyl)ferrocenyl]ethyl}cyclohexylphosphane] forms four-coordinate complexes with IrI and RhI. The tridentate ligand assumes different conformations in the derivatives [Rh(CO)(Pigiphos)]OTf (4) and [IrCl(Pigiphos)] (1b), the latter also showing a drastic deviation from the square-planar geometry. Reactivity studies have focussed on the more reactive 1b. The HCl and O2 adducts have been characterized in solution. (literal)

Prodotto di

• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)
• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)

Autore CNR

• PIERLUIGI BARBARO (Unità di personale interno)

Incoming links:

Prodotto

• Institute of chemistry of organometallic compounds (ICCOM) (Istituto)
• Sostenibilità in processi selettivi: catalizzatori, metodologie e approcci innovativi (PM.P03.002.001) (Modulo)

Autore CNR di

• PIERLUIGI BARBARO (Unità di personale interno)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• European journal of inorganic chemistry (Rivista)