Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a ligand (Articolo in rivista)

Type
Label
  • Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a ligand (Articolo in rivista) (literal)
Anno
  • 2002-01-01T00:00:00+01:00 (literal)
Alternative label
  • Ienco, Andrea; Mealli, Carlo; Dodoff, Nikolay I. (2002)
    Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a ligand
    in Zeitschrift für Naturforschung. B, A journal of chemical sciences
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Ienco, Andrea; Mealli, Carlo; Dodoff, Nikolay I. (literal)
Pagina inizio
  • 865 (literal)
Pagina fine
  • 867 (literal)
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  • 57b (literal)
Rivista
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
  • 4 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • CNR, ICCOm, I-50139 Florence, Italy Bulgarian Acad Sci, Inst Mol Biol, Sofia 1113, Bulgaria (literal)
Titolo
  • Synthesis and Structure of the First Transition Metal Complex with Methanesulfonylhydrazine as a ligand (literal)
Abstract
  • The article reports the first transition metal complex of methanesulfonylhydrazine, a molecule known for important pharmacological and chemical applications. The complex [ZnCl2(MSH)(2)], MSH = CH3SO2NHNH2, has been synthesized and its structure characterized by means of Xray analysis. The coordination geometry is pseudo-tetrahedral and the ligand MSH adopts a conformation that was found by previous ab initio calculations to be a transition state and not a stationary point for the free ligand. (literal)
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