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Structural and Electronic Features of o-Phenylenediamido Complexes of Group 6 Metals in Different Oxidation States (Articolo in rivista)

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Structural and Electronic Features of o-Phenylenediamido Complexes of Group 6 Metals in Different Oxidation States (Articolo in rivista) (literal)

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Galindo, Agustin; Ienco, Andrea; Mealli, Carlo (2002)
Structural and Electronic Features of o-Phenylenediamido Complexes of Group 6 Metals in Different Oxidation States
in Comments on modern chemistry. Part A, Comments on inorganic chemistry; TAYLOR & FRANCIS LTD, 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON (Regno Unito)
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Univ Sevilla, Dept Quim Inorgan, Seville, Spain CNR, ICCOM, I-50132 Florence, Italy (literal)

Titolo

Structural and Electronic Features of o-Phenylenediamido Complexes of Group 6 Metals in Different Oxidation States (literal)

Abstract

Reported complexes of general formula L4M(phenylenediamido-o), where M is a metal of group 6 in various oxidation states (VI, IV, H and 0), are analyzed. The possible structural deviations from the most symmetric pseudo-octahedral structure (the one with the, chelate in the equatorial plane) are evaluated, case by case, in view of their electronic origin. The analysis is based on systematic DFT calculations and their qualitative MO interpretation based on perturbation theory concepts. (literal)

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