A biomimetic synthesis of sacculatane diterpenoids. (Articolo in rivista)

Type
Label
  • A biomimetic synthesis of sacculatane diterpenoids. (Articolo in rivista) (literal)
Anno
  • 2008-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/hlca.200890031 (literal)
Alternative label
  • Grinco M; Kulcitki V.;, N. Ungur, Vlad P.F.; Gavagnin M.; Castelluccio F.; Cimino G. (2008)
    A biomimetic synthesis of sacculatane diterpenoids.
    in Helvetica chimica acta
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Grinco M; Kulcitki V.;, N. Ungur, Vlad P.F.; Gavagnin M.; Castelluccio F.; Cimino G. (literal)
Pagina inizio
  • 249 (literal)
Pagina fine
  • 258 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 91 (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
  • Scopus (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Acad Stiinte Moldovei, Inst Chem, Kishinev, Moldova; CNR, Ist Chim Biomol, I-80078 Pozzuoli, NA, Italy (literal)
Titolo
  • A biomimetic synthesis of sacculatane diterpenoids. (literal)
Abstract
  • The biomimetic synthesis of sacculatane-type epimeric compounds 14a and 14b is reported. The key synthetic step is the low-temperature superacidic cyclization of (all-E)-omega-acetoxygeranylgeraniol 12 obtained in nine steps from geranyllinalool (13). The 19-acetoxysacculata-7,17-dien-11-ol (14a) could be an important and convenient starting compound for the synthesis of other sacculatane diterpenoids. (literal)
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Autore CNR

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