Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases (Articolo in rivista)

Type

• Prodotto della ricerca (Classe)
• Articolo in rivista (Classe)

Label

• Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases (Articolo in rivista) (literal)

Anno

• 2007-01-01T00:00:00+01:00 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi

• 10.1002/chir.20386 (literal)

Alternative label

• Patti A.; Pedotti S.; Sanfilippo C. (2007)
  Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases
  in Chirality (N.Y., N.Y. Print)
  (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori

• Patti A.; Pedotti S.; Sanfilippo C. (literal)

Pagina inizio

• 344 (literal)

Pagina fine

• 351 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#url

• http://onlinelibrary.wiley.com/doi/10.1002/chir.20386/pdf (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume

• 19 (literal)

Rivista

• Chirality (Rivista)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali

• 7 (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroFascicolo

• 5 (literal)

Note

• ISI Web of Science (WOS) (literal)
• Scopu (literal)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni

• Istituto di Chimica Biomolecolare -Sez. di CAtania Via del Santuario, 110 I-95028 Valverde CT, Italy (literal)

Titolo

• Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases (literal)

Abstract

• The direct HPLC enantiomeric separation of several ferrocenylalcohols on the commercially available Chiralcel OD and Chiralcel OJ columns has been evaluated in normal-phase mode. Almost all the compounds were resolved on one or both chiral stationary phases (CSPs) with separation factor (alpha) ranging from 1.06 to 2.88 while the resolution (Rs) varied from 0.63 to 12.70 In the separation of the alpha-ferrocenylalcohols 1a-e and the phenyl analogues 2a-e, which were all resolved except 1c, a similar trend in the retention behavior for the two series of alcohols was evidenced and the selectivity was roughly complementary on the two investigated CSP. For three ferrocenylacohols, chosen as model compounds, the influence of the mobile phase composition and temperature on the enantioseparation were investigated and additional information on the chiral recognition mechanism were deduced from the chromatographic behavior of their acetylderivatives. (literal)

Prodotto di

• Istituto di chimica biomolecolare (ICB) (Istituto)
• Sintesi di molecole multifunzionalizzate ad attività antitumorale. (PM.P01.009.003) (Modulo)

Autore CNR

• SONIA PEDOTTI (Unità di personale interno)
• CLAUDIA SANFILIPPO (Persona)
• ANGELA PATTI (Persona)

Insieme di parole chiave

• Parole chiave di "Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases" (Insieme di parole chiave)

Incoming links:

Autore CNR di

• CLAUDIA SANFILIPPO (Persona)
• SONIA PEDOTTI (Unità di personale interno)
• ANGELA PATTI (Persona)

Prodotto

• Istituto di chimica biomolecolare (ICB) (Istituto)
• Sintesi di molecole multifunzionalizzate ad attività antitumorale. (PM.P01.009.003) (Modulo)

Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#rivistaDi

• Chirality (Rivista)

Insieme di parole chiave di

• Parole chiave di "Comparative HPLC enantioseparation of ferrocenylalcohols on two cellulose-based chiral stationary phases" (Insieme di parole chiave)