http://www.cnr.it/ontology/cnr/individuo/prodotto/ID15557
Chemistry of Glossodoris nudibranchs: specific occurrence of 12-keto scalaranes. (Articolo in rivista)
- Type
- Label
- Chemistry of Glossodoris nudibranchs: specific occurrence of 12-keto scalaranes. (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1007/s10886-007-9387-x (literal)
- Alternative label
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- E. Manzo; M. Gavagnin; M. J. Somerville; S.-C. Mao; M. L. Ciavatta; E. Mollo; P. J. Schupp; M. J. Garson; Y.-W. Guo; G. Cimino. (literal)
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- Rivista
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- Note
- Scopu (literal)
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto di Chimica Biomolecolare, CNR, Via Campi Flegrei 34, 80078 Pozzuoli (Na), Italy
School of Molecular and Microbial Sciences, The University of Queensland,
Brisbane, Queensland 4072, Australia
State Key Laboratory of Drug Research, Institute of Materia Medica, Shanghai,
Institute for Biological Sciences, Chinese Academy of Sciences, 201203 Shanghai,
People's Republic of China
University of Guam, Marine Laboratory, UOG Station- Mangilao, Guam 96923, USA (literal)
- Titolo
- Chemistry of Glossodoris nudibranchs: specific occurrence of 12-keto scalaranes. (literal)
- Abstract
- With the aim of establishing whether the oxidation of the tricyclic carbon
skeleton of scalaradial (1) is specific to Glossodoris mollusks, the chemical investigation of
specimens of Glossodoris pallida from two distinct geographical areas (China and Guam)
and of Glossodoris vespa and Glossodoris averni from Eastern Australia was performed.
12-Deacetoxy-12-oxo-scalaradial (4), recently reported from another Glossodoris nudibranch,
was the main metabolite of G. pallida from China, G. vespa, and G. averni. A
series of scalarane compounds 3 and 5-11, including the unprecedented 12,16-deacetoxy-
12-oxo-scalarafuran 5, was isolated from the mollusks. Interestingly, a population of G.
pallida from Guam displayed a different scalarane pattern that was characterized by
scalaradial (1), deacetyl scalaradial (2), and deoxoscalarin (3), thus confirming previous
reports. The specific occurrence of 12-keto-derivatives in some nudibranchs of the genus
Glossodoris is discussed. (literal)
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