Chiral, enantiopure, aluminum(III) and titanium(IV) azatranes (Articolo in rivista)

Type
Label
  • Chiral, enantiopure, aluminum(III) and titanium(IV) azatranes (Articolo in rivista) (literal)
Anno
  • 2006-01-01T00:00:00+01:00 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
  • 10.1002/ejic.200500657 (literal)
Alternative label
  • Forcato M., Lake F., Blazquez M.M., Renner P., Crisma M., Gade L.H., Licini G., Moberg C. (2006)
    Chiral, enantiopure, aluminum(III) and titanium(IV) azatranes
    in European journal of inorganic chemistry (Print)
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Forcato M., Lake F., Blazquez M.M., Renner P., Crisma M., Gade L.H., Licini G., Moberg C. (literal)
Pagina inizio
  • 1032 (literal)
Pagina fine
  • 1040 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • Citazioni WOS: 3 Impact Factor 2006: 2.704 Coautore (literal)
Rivista
Note
  • ISI Web of Science (WOS) (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Università degli Studi di Padova, Dipartimento di Scienze Chimiche, 35131 Padova, Italy; Department of Chemistry, Organic Chemistry, Royal Institute of Technology, Stockholm, Sweden; Anorganisch-Chemisches Institut, Ruprecht-Karls-Universitat Heidelberg, 69120 Heidelberg, Germany; Istituto di Chimica Biomolecolare, CNR, 35131 Padova, Italy (literal)
Titolo
  • Chiral, enantiopure, aluminum(III) and titanium(IV) azatranes (literal)
Abstract
  • Al-III and Ti-IV complexes of C-3-symmetric tetradentate trisamidoamme ligands with trigonal bipyramidal coordination geometry, containing chlorine or dialkylamido groups, or with a free coordination site in the apical position, have been synthesised by salt metathesis and amine elimination. Products with threefold symmetry were generally obtained for tetravalent titanium, whereas for the aluminium complexes either asymmetric structures with two of the three podand arms taking part in coordination to the metal or symmetric arrangements possessing the full threefold symmetry were formed depending on the steric properties of the ligands. (literal)
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