http://www.cnr.it/ontology/cnr/individuo/prodotto/ID15083
A Chiroptical Molecular Switch with Distinct Chiral and PhotochromicEntities and Its Application in Optical Switching of a Cholesteric LiquidCrystal (Articolo in rivista)
- Type
- Label
- A Chiroptical Molecular Switch with Distinct Chiral and PhotochromicEntities and Its Application in Optical Switching of a Cholesteric LiquidCrystal (Articolo in rivista) (literal)
- Anno
- 2004-01-01T00:00:00+01:00 (literal)
- Alternative label
van Delden R. A. , Mecca T., Rosini C., Feringa B. L. (2004)
A Chiroptical Molecular Switch with Distinct Chiral and PhotochromicEntities and Its Application in Optical Switching of a Cholesteric LiquidCrystal
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- van Delden R. A. , Mecca T., Rosini C., Feringa B. L. (literal)
- Pagina inizio
- Pagina fine
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
- Note
- ISI Web of Science (WOS) (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Department of Organic Chemistry
Stratingh Institute, University of Groningen
Dipartimento di Chimica
Università della Basilicata
C.N.R.Istituto di Chimica Biomolecolare (Sez. di Catania) (literal)
- Titolo
- A Chiroptical Molecular Switch with Distinct Chiral and PhotochromicEntities and Its Application in Optical Switching of a Cholesteric LiquidCrystal (literal)
- Abstract
- Two new structurally related
photoswitches are described, in which
azobenzene photochromism is combined
with the chirality of a 2,2-dihydroxy-
1,1-binaphthyl unit. In system 1
the chiral binaphthyl moiety is bridged
by a methylene tether, locking the
biaryl chirality while in system 2 the
biaryl core is unbridged and has considerable
conformational flexibility.
Both compound are capable of inducing
cholesteric liquid crystalline phases
and proved to be good photoswitches
both in solution and in a liquid crystalline
matrix. Compound 2 is capable of
completely reversing the liquid crystalline
chirality which is unique for a chiroptical
molecular switch where the
switching unit and the chiral moiety
are separate entities. (literal)
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