A Short Entry to Novel (2)-Methyl Branched 4a-Carbafuranoses (Articolo in rivista)

Type
Label
  • A Short Entry to Novel (2)-Methyl Branched 4a-Carbafuranoses (Articolo in rivista) (literal)
Anno
  • 2003-01-01T00:00:00+01:00 (literal)
Alternative label
  • Rassu G., Auzzas L., Zambrano V., Burreddu P., Battistini L., Curti C. (2003)
    A Short Entry to Novel (2)-Methyl Branched 4a-Carbafuranoses
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rassu G., Auzzas L., Zambrano V., Burreddu P., Battistini L., Curti C. (literal)
Pagina inizio
  • 1665 (literal)
Pagina fine
  • 1670 (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#numeroVolume
  • 14 (literal)
Note
  • ISI Web of Science (WOS) (literal)
Titolo
  • A Short Entry to Novel (2)-Methyl Branched 4a-Carbafuranoses (literal)
Abstract
  • A concise, diastereoselective synthesis of 2-C-methyl-4a-carba-beta-D-lyxofuranose (13) and 2-C-methyl-4a-carba-beta-D-arabinofuranose (14), two novel representatives of the understated branched-chain carbasugar family, is presented. The construction is founded on the sequential execution of two strategic carbon-carbon bond-forming reactions, a vinylogous crossed aldol addition (1 + 2 vs 3), and a rare silylative cycloaldolization (8 vs 9 + 10). (literal)
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