Electroactive C2 symmetry receptors based on the biphenyl scaffold and tetrathiafulvalene (TTF) units (Progetti)

Type
Label
  • Electroactive C2 symmetry receptors based on the biphenyl scaffold and tetrathiafulvalene (TTF) units (Progetti) (literal)
Anno
  • 2005-01-01T00:00:00+01:00 (literal)
Alternative label
  • Giovanna Delogu, Davide Fabbri, Maria Antonietta Dettori, Marc Sallé, Franck Le Derf, Maria-Jesus Blesa, Magali Allain (2005)
    Electroactive C2 symmetry receptors based on the biphenyl scaffold and tetrathiafulvalene (TTF) units
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Giovanna Delogu, Davide Fabbri, Maria Antonietta Dettori, Marc Sallé, Franck Le Derf, Maria-Jesus Blesa, Magali Allain (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#altreInformazioni
  • The synthesis of a family of biphenyl-tetrathiafulvalene derivatives incorporating a binding site has been carried out in good to moderate yields through functionalization of the hydroxylated biphenyl scaffold. 1H-NMR and cyclic-voltammetry studies demonstrate the critical importance of the nature of the substitution on the conformational rigidity and on the electrochemical behaviour of the resulting biphenyl-TTF assemblies. This feature is underlined by an original electrochemical recognition process upon binding of Pb2+, correlated to conformational changes occurring upon metal cation complexation. (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • - progetto COST (D31/0014/05 2005-2009) dal titolo: ‘Synthesis beyond the redox-active tetrathiafulvalene (TTF) molecole: from a topological control in TTF-based macrocycles, towards functional chemical systems’. (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
  • Istituto CNR di Chimica Biomolecolare di Sassari; Laboratoire Chimie, Ingénierie Moléculaire et Matériaux d’Angers (CIMMA), UMR CNRS-Angers France (literal)
Titolo
  • Electroactive C2 symmetry receptors based on the biphenyl scaffold and tetrathiafulvalene (TTF) units (literal)
Descrizione sintetica
  • COST. Cost Action N°: D31. WG-Number: 014. Duration 4 years: 2005-2009. Titolo del progetto: Synthesis Beyond the redox-active tetrathiafulvalene (TTF) molecole. From a topological control in TTF-based Macrocycles, towards Functional chemical Systems. Principal Applicant: Laboratoire de Chemie, Ingegnerie moleculaire et Materiaux d'Angers (CIMMA), CNRS 6200, UFR Sciences, Universite' d'Angers. (France), CNR Institution: CNR-ICB Institute of Biomolecular Chemistry- Sassari (Italy). Responsabile italiano del Progetto: Dr. Giovanna Delogu. (literal)
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