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Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy (Articolo in rivista)
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- Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy (Articolo in rivista) (literal)
- Anno
- 2007-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.1103/PhysRevB.75.153102 (literal)
- Alternative label
Payne, DJ; Egdell, RG; Paolicelli, G; Offi, F; Panaccione, G; Lacovig, P; Monaco, G; Vanko, G; Walsh, A; Watson, GW; Guo, J; Beamson, G; Glans, PA; Learmonth, T; Smith, KE (2007)
Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy
in Physical review. B, Condensed matter and materials physics
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Payne, DJ; Egdell, RG; Paolicelli, G; Offi, F; Panaccione, G; Lacovig, P; Monaco, G; Vanko, G; Walsh, A; Watson, GW; Guo, J; Beamson, G; Glans, PA; Learmonth, T; Smith, KE (literal)
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- ISI Web of Science (WOS) (literal)
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- Inorgan Chem Lab, Oxford OX1 3QR, England; CNR, INFM, Natl Res Ctr, I-41100 Modena, Italy; Univ Roma Tre, CNISM, I-00146 Rome, Italy; Univ Roma Tre, Dipartimento Fis, I-00146 Rome, Italy; CNR, INFM, Lab TASC, I-34012 Trieste, Italy; Sincrotrone Trieste, SCpA, I-34012 Trieste, Italy; European Synchrotron Radiat Facil, F-38042 Grenoble 9, France; Trinity Coll Dublin, Sch Chem, Dublin 2, Ireland; Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA; NCESS, Daresbury Lab, Warrington WA4 4AD, Cheshire, England; Boston Univ, Dept Phys, Boston, MA 02215 USA (literal)
- Titolo
- Nature of electronic states at the Fermi level of metallic beta-PbO2 revealed by hard x-ray photoemission spectroscopy (literal)
- Abstract
- The nature of electronic states at the Fermi energy in metallic beta-PbO2 has been identified by hard x-ray photoemission spectroscopy (HXPS) combined with x-ray emission spectroscopy and density-functional theory calculations. Pb 6s states are strongly enhanced in HXP spectra, allowing us to locate the Fermi level above the top of the valence band. The occupied conduction-band states have significant Pb 6s character, although the major 6s contribution to the density of states is found 9 eV below the Fermi energy. The enormous potential of HXPS for the study of s states in oxides is emphasized. (literal)
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