cis and trans Influences in Pt(PPh3)2 Complexes (Abstract/Poster in convegno)

Type
Label
  • cis and trans Influences in Pt(PPh3)2 Complexes (Abstract/Poster in convegno) (literal)
Anno
  • 2009-01-01T00:00:00+01:00 (literal)
Alternative label
  • Rigamonti, L.; Rusconi, M.; Manassero, C.; Manassero, M.; Forni, A.; Pasini, A. (2009)
    cis and trans Influences in Pt(PPh3)2 Complexes
    in XXIII Congresso Nazionale della Società Chimica Italiana, Sorrento
    (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
  • Rigamonti, L.; Rusconi, M.; Manassero, C.; Manassero, M.; Forni, A.; Pasini, A. (literal)
Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
  • The cis and the trans influences are important tools to rationalize the bond strengths in complexes. In cis/trans- [PtIIXY(PPh3)2] compounds (X and Y are anionic ligands) the variations of the Pt-P bond strengths can be related to the 1JPtP values, which depend on both the cis and trans influences of X and Y. Analysing the coupling constants of a series of cis and trans-[PtIIXY(PPh3)2] compounds these influences can be rationalized and quantified. The structural trans and cis influences are less manifest, as shown by several crystal structures, which have been determined. A theoretical study will also be described, in order to fully comprehend these systems. (literal)
Titolo
  • cis and trans Influences in Pt(PPh3)2 Complexes (literal)
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