http://www.cnr.it/ontology/cnr/individuo/prodotto/ID105496
Tailoring Optical Properties of Blue-gap Poly(p-phenylenevinylene)s for LEDs Applications (Articolo in rivista)
- Type
- Label
- Tailoring Optical Properties of Blue-gap Poly(p-phenylenevinylene)s for LEDs Applications (Articolo in rivista) (literal)
- Anno
- 2010-01-01T00:00:00+01:00 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#doi
- 10.4028/www.scientific.net/AST.75.118 (literal)
- Alternative label
Giangregorio M. M. , Losurdo M. , Capezzuto P. , Bruno G. , Cardone A. , Martinelli C., Farinola G. M. , Babudri F. , Naso. F. (2010)
Tailoring Optical Properties of Blue-gap Poly(p-phenylenevinylene)s for LEDs Applications
in Advances in science and technology (Online)
(literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#autori
- Giangregorio M. M. , Losurdo M. , Capezzuto P. , Bruno G. , Cardone A. , Martinelli C., Farinola G. M. , Babudri F. , Naso. F. (literal)
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- Rivista
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#note
- 13-18 Giugno 2010, Symposium FJ: Materials and Technologies for Solid State Lighting, Poster Presentation FJ:P04, pag. 104 (literal)
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#pagineTotali
- Note
- Http://www.cnr.it/ontology/cnr/pubblicazioni.owl#affiliazioni
- Istituto di Metodologie Inorganiche e Plasmi, IMIP-CNR, Via E. Orabona 4, 70126 Bari, Italy
Istituto di Chimica dei Composti Organometallici, ICCOM-CNR di Bari, Via E. Orabona 4, 70126 Bari, Italy
Dipartimento di Chimica, Università degli studi di Bari,Via E. Orabona 4, 70126 Bari, Italy (literal)
- Titolo
- Tailoring Optical Properties of Blue-gap Poly(p-phenylenevinylene)s for LEDs Applications (literal)
- Abstract
- There has been growing interest in developing new semiconducting polymers for applications in optoelectronics (OLEDs) due to their exceptional processability and appealing characteristic of manipulating electronic and optical properties by tuning of molecular structure and self-assembling. This study is an investigation on the interplay among supermolecular organization and optical properties of thin films of the poly[2-(2-ethylhexyloxy)-5-methoxy]-1, 4-phenylenedifluorovinylene
(MEH-PPDFV) conjugated polymer, which has fluorinated vinylene units. This interplay is elucidated exploiting atomic force microscopy, spectroscopy ellipsometry, photoluminescence and electroluminescence. Thin films of MEH-PPDFV have been deposited by drop casting on indiumtin- oxide (ITO), quartz and glass substrates. The dependence of polymer chains self-organization and morphology on substrate surface is presented. Furthermore, it is demonstrated that the presence
of F-atoms in the vinylene units of the MEH-PPDFV yields a blue optical band gap with the maximum of the fundamental HOMO-LUMO transition at 331 nm and photoluminescence at 458 nm. The OLED built with the above polymer shows a very stable blue-greenish electroluminescence that is also achieved at 504 nm. (literal)
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